The question you should ask is not "what can Dreamweaver do", it's "what can I do with Dreamweaver".
wanted to know if I can use dreamweaver to build websites like this one here.
Yes, you can build a website like that with Dreamweaver, but you'd need to be quite skilled with HTML/CSS/PHP/MySQL to do so. In this particular case, note the disclaimer at the bottom -
Copyright © 2014 SupRiverSurfer. Proudly powered by WordPress. BoldR design by Iceable Themes.
This means that the site is a Wordpress site, and can be built entirely within Wordpress' user interface. You wouldn't need Dreamweaver at all.